While paints and other coatings contribute to the esthetics and utility of many things, these benefits often must be weighed against environmental costs. Spray coating operations currently release pollutant gases into the environment, with resultant potential health problems for production workers and the community as a whole. Thus, for example, the two auto assembly plants in Delaware produce, between them, about 40% of the state's toxic emissions. This is due, almost entirely, to their painting operations. About one billion pounds of organic solvents, from liquid coating operations, are currently being released into the environment by chemical process and manufacturing industries each year. Government legislation has made the control of these pollutants an industrial priority and has mandated drastic reductions in volatile organic solvent (VOC) content. New formulations produced to meet these requirements have far more complicated rheological and film formation behavior, and generally exhibit less good coating performance. Candidate replacement low-VOC coatings perform less well, however, and are more prone to defects such as sagging (drip marks), blisters, and "orange-peel." Development of such new coating products and processes that are economically competitive, use minimal amounts of material, produce final defect-free coatings in actual on-line operations, without adverse environmental impact, is a formidable scientific and engineering challenge.
Until such time as liquid coatings dry and become immobile, their flow behavior needs to be predicted. Basic questions involve the wetting and spreading of thin liquid layers as they flow on geometrically-complex surfaces. At the same time, the important physical properties of the liquid, such as viscosity and surface tension, are continually changing, as it dries. Over the past seven years our research group has built mathematical models for these complicated processes. The resulting set of coupled nonlinear partial differential equations in space and time can then be solved numerically. Improvements in computational hardware and efficient new computer algorithms have made it possible to produce realistic flow simulations on desk-top workstations. Our computer models are continually being extended in order to include more realistic descriptions of important physical and chemical effects. Final coating defects, such as sagging, blisters and ribs, can be visualized, as they develop, in the simulation output, and their origin can be related to rheological, processing, and geometric parameters. Permissible changes in these parameters can then be investigated to identify performance improvements. Theoretical predictions are validated by microscopic and other experimental measurements. Applications include the analysis of spray, curtain, roll, and other industrial coating operations.